ÀíÏëÆøÌå״̬·½³Ì

ÃèдÀíÏëÆøÌå״̬±ä»¯¹æÂɵķ½³Ì¡£¶ÔÓÚÒ»¶¨ÖÊÁ¿µÄÆøÌ壬¿ÉÒÔÓÃѹǿpºÍÌå»ýVÀ´ÃèÊöËüµÄƽºâ̬£¬¶øζÈTÊÇpºÍVµÄº¯Êý£¬F(T£¬p£¬V)=0¡£Õâ¸ö¹Øϵʽ½Ð×öÆøÌåµÄ״̬·½³Ì£¬ËüµÄ¾ßÌåÐÎʽÐèÓÉʵÑéÈ·¶¨¡£

²£Òâ¶ú¶¨ÂÉ

ÓֳƲ£Òâ¶ú¡ªÂíÂÔÌض¨ÂÉ£¬ÊÇÓ¢¹ú»¯Ñ§¼ÒR.²£Òâ¶úÔÚ1662ÄêºÍ·¨¹úÎïÀíѧ¼ÒE.ÂíÂÔÌØÔÚ1679Äê·Ö±ð¶ÀÁ¢·¢Ïֵġ£ËüµÄÄÚÈÝÊÇ£ºÒ»¶¨ÖÊÁ¿µÄÆøÌ壬µ±Î¶ȱ£³Ö²»±äʱ£¬Ñ¹Ç¿ºÍÌå»ý³É·´±ÈÇҳ˻ýÊÇÒ»¸ö³£Êý

p1V1=p2V2=p3V3=¡­»òpV=C¡£

³£ÊýC ÔÚ²»Í¬Î¶ÈʱÓв»Í¬ÊýÖµ¡£

´óÁ¿ÊµÑé½á¹û±íÃ÷£¬¸Ã¶¨ÂɶÔÀíÏëÆøÌåÍêÈ«ÕýÈ·¡£¶ÔÓÚ¸÷ÖÖʵ¼ÊÆøÌ壬ֻҪËüµÄѹǿ²»Ì«¸ß£¬Î¶Ȳ»Ì«µÍ£¬¶¼½üËƵØ×ñ´Ó´Ë¶¨ÂÉ£»ÆøÌåµÄѹǿԽµÍ£¬Ëü×ñ´Ó²£Òâ¶ú¶¨Âɵľ«È·¶È¾ÍÔ½¸ß¡£

¸Ç£­ÂÀÈø¿Ë¶¨ÂÉ

Ò»¶¨ÖÊÁ¿µÄÆøÌ壬µ±Ìå»ý²»±äʱ£¬ËüµÄѹǿËæζÈ×÷ÏßÐԱ仯£º

p=p0(1+¦Át)£¬p0

ÊÇ0¡ãCʱµÄÆøÌåѹǿ£¬pÊÇt¡ãCʱµÄÆøÌåѹǿ£¬¦ÁÊÇÔÚÆøÌåÌå»ý²»±äʱµÄѹǿϵÊý¡£¶ÔÓÚÀíÏëÆøÌ壬¦ÁµÄÊýֵΪһÆÕÊʳ£Êý£¬ÆäֵΪ1/273.15£¬ÓÚÊÇ

ÈôÁîT=t£«273.15£¬ÔòÉÏʽ¼ò»¯Îª

pt=p0¦ÁT£¬T

¼´ÎªÈÈÁ¦Ñ§Î±꣬Æ䵥λÊÇ¿ª¶ûÎÄ (K)£»t=0ʱ£¬T0=273.15K¡£

ÀíÏëÆøÌå״̬·½³Ì¡¡¸ù¾Ý²£Òâ¶ú¶¨ÂÉ¡¢°¢·üÙ¤µÂÂÞ¶¨ÂɺÍÀíÏëÆøÌåαêµÄ¶¨Ò壬¿ÉÒÔÈ·¶¨²£Òâ¶ú¶¨ÂÉÖг£ÊýCÓëζȵĹØϵ£¬²¢¿Éµ¼³ö

ʽÖÐp0¡¢V0¡¢T0Ϊ±ê×¼×´¿öÏÂһĦ¶ûÀíÏëÆøÌåµÄѹǿ¡¢Ìå»ý¡¢Î¶ȣ»vΪĦ¶ûÊý¡£Òò´Ë£¬µÄÊýÖµ¶Ô¸÷ÖÖÆøÌ嶼һÑù¡£¸ÃÊýÖµ½ÐĦ¶ûÆøÌå³£Êý²¢ÓÃr±íʾ£º

ÓÚÊÇʽÖÐM´ú±íÆøÌåµÄÖÊÁ¿£¬¦Ì ÊÇÆøÌåµÄ·Ö×ÓÁ¿¡£Õâ¾ÍÊÇÀíÏëÆøÌå״̬·½³Ì¡£

ÔÚѹǿΪ¼¸¸ö´óÆøѹÒÔÏÂʱ£¬¸÷ÖÖʵ¼ÊÆøÌåÒ»°ã¶¼½üËƵØ×ñ´ÓÀíÏëÆøÌå״̬·½³Ì¡£Ñ¹Ç¿Ô½µÍ£¬·ûºÏµÄ³Ì¶ÈÔ½¸ß¡£ÔÚѹǿÇ÷ÓÚÁãµÄ¼«ÏÞÇé¿öÏ£¬Ò»ÇÐÆøÌ嶼ÑϸñµØ×ñ´ÓËü¡£¸ù¾ÝÀíÏëÆøÌåÄ£ÐÍ£¬´ÓÆøÌå·Ö×ÓÔ˶¯ÂÛ³ö·¢£¬Ò²¿ÉÒÔÍƵ¼³ö¸ÃÎï̬·½³Ì¡£

Ħ¶ûÆøÌå³£ÊýR

RµÄÊýÖµ¿ÉÓÉһĦ¶ûÀíÏëÆøÌåÔÚË®µÄÈýÏàµã (273.16K)¼°Ò»¸ö´óÆøѹϵÄÌå»ýÍƳö¡£Ò²¿ÉÒÔÓÉһĦ¶ûÀíÏëÆøÌåÔÚ±ùµã (273.15K)¼°Ò»¸ö´óÆøѹϵÄÌå»ýV0ÍƳö¡£ÓÃV0À´ÍÆËãµÄÔ­ÒòÊÇ V0¿É¸ù¾ÝʵÑé½á¹ûÇóµÃ±È½Ï׼ȷµÄÊýÖµ¡£ÓÉ

V0=22.41383¡Á10-3m3/mol

¿ÉËãµÃ

r=8.31441¡À0.00026J/(mol¡¤K)¡£